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Nanoscale Borromean Rings Stuart J. Cantrill, Kelly S. Chichak, Andrea J. Peters, and J. Fraser Stoddart pp 1–9 DOI: 10.1021/ar040226x |
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Confusion Approach to Porphyrinoid Chemistry Alagar Srinivasan and Hiroyuki Furuta pp 10–20 DOI: 10.1021/ar0302686 |
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Investigations on Butterfly Fe/S Cluster S-Centered Anions (μ-S-)2Fe2(CO)6, (μ-S-)(μ-RS)Fe2(CO)6, and Related Species Li-Cheng Song pp 21–28 DOI: 10.1021/ar030004j |
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Computational Studies on the Cyclizations of Enediynes, Enyne-Allenes, and Related Polyunsaturated Systems Peter R. Schreiner, Armando Navarro-Vázquez, and Matthias Prall pp 29–37 DOI: 10.1021/ar020270h |
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Ordering Fullerene Materials at Nanometer Dimensions Dirk M. Guldi, Francesco Zerbetto, Vasilios Georgakilas, and Maurizio Prato pp 38–43 DOI: 10.1021/ar040222s |
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Catalytic Transmetalation from Group 6 Fischer Carbene Complexes: An Emerging Powerful Tool in Organic Synthesis Mar Gómez-Gallego, María José Mancheño, and Miguel A. Sierra pp 44–53 DOI: 10.1021/ar040005r |
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Bioinspired Hydrogen Bond Motifs in Ligand Design: The Role of Noncovalent Interactions in Metal Ion Mediated Activation of Dioxygen A. S. Borovik pp 54–61 DOI: 10.1021/ar030160q |
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How to Hide Zinc in a Small Protein Claudia A. Blindauer and Peter J. Sadler pp 62–69 DOI: 10.1021/ar030182c |
Issue 02
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Rigid-Rod Molecules in Biomembrane Models: From Hydrogen-Bonded Chains to Synthetic Multifunctional Pores Naomi Sakai, Jiri Mareda, and Stefan Matile pp 79–87 DOI: 10.1021/ar0400802 |
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Benziporphyrins: Exploring Arene Chemistry in a Macrocyclic Environment Marcin Stȩpień and Lechosław Latos-Grażyński pp 88–98 DOI: 10.1021/ar040189+ |
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Optical Excitations in Organic Dendrimers Investigated by Time-Resolved and Nonlinear Optical Spectroscopy T. G. Goodson, III pp 99–107 DOI: 10.1021/ar020247w |
Design and Study of Phosphocavitands A New Family of Cavity SystemsEduard E. Nifantyev, Vera I. Maslennikova, and Roman V. Merkulov pp 108–116 DOI: 10.1021/ar0401810 |
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Structure, Orientation, and Conformational Changes in Transmembrane Domains of Multidrug Transporters Catherine Vigano, Liliana Manciu, and Jean-Marie Ruysschaert pp 117–126 DOI: 10.1021/ar040021o |
Metalloporphyrines as Active Site Analogues Lessons from Enzymes and Enzyme ModelsWolf-D. Woggon pp 127–136 DOI: 10.1021/ar0400793 |
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Optical Microscopy Studies of Dynamics within Individual Polymer-Dispersed Liquid Crystal Droplets Daniel A. Higgins, Jeffrey E. Hall, and Aifang Xie pp 137–145 DOI: 10.1021/ar040106p |
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Interactions of Metal−Metal-Bonded Antitumor Active Complexes with DNA Fragments and DNA Helen T. Chifotides and Kim R. Dunbar pp 146–156 DOI: 10.1021/ar0302078 |
Issue 03
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Transient-State Kinetic Approach to Mechanisms of Enzymatic Catalysis Harvey F. Fisher pp 157–166 DOI: 10.1021/ar040218g |
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Ferritins: Dynamic Management of Biological Iron and Oxygen Chemistry Xiaofeng Liu and Elizabeth C. Theil pp 167–175 DOI: 10.1021/ar0302336 |
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Reticular Chemistry: Occurrence and Taxonomy of Nets and Grammar for the Design of Frameworks Nathan W. Ockwig, Olaf Delgado-Friedrichs, Michael O'Keeffe, and Omar M. Yaghi pp 176–182 DOI: 10.1021/ar020022l |
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Disulfido Metal Carbonyl Complexes Containing Manganese Richard D. Adams, O-Sung Kwon, and Shaobin Miao pp 183–190 DOI: 10.1021/ar0402457 |
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Arginase: Structure, Mechanism, and Physiological Role in Male and Female Sexual Arousal David W. Christianson pp 191–201 DOI: 10.1021/ar040183k |
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A Novel Method for the Simultaneous, Titrant-Free Control of pH and Calcium Phosphate Mass Yield A. K. Lynn and W. Bonfield pp 202–207 DOI: 10.1021/ar040234d |
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Substrate Interactions with the Nitrogenase Active Site Patricia C. Dos Santos, Robert Y. Igarashi, Hong-In Lee, Brian M. Hoffman, Lance C. Seefeldt, and Dennis R. Dean pp 208–214 DOI: 10.1021/ar040050z |
Issue 04
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Molecular Architectures Christopher A. Reed pp 215–216 DOI: 10.1021/ar050039e |
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Crystallized Frameworks with Giant Pores: Are There Limits to the Possible? Gérard Férey, Caroline Mellot-Draznieks, Christian Serre, and Franck Millange pp 217–225 DOI: 10.1021/ar040163i |
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Inorganic−Organic Hybrid Molecular Architectures of Cyanometalate Host and Organic Guest Systems: Specific Behavior of the Guests Shin-ichi Nishikiori, Hirofumi Yoshikawa, Yuriko Sano, and Toschitake Iwamoto pp 227–234 DOI: 10.1021/ar0401707 |
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Fullerene−Porphyrin Constructs Peter D. W. Boyd, Christopher A. Reed pp 235–242 DOI: 10.1021/ar040168f |
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Ligand Design in Multimetallic Architectures: Six Lessons Learned Peter J. Steel pp 243–250 DOI: 10.1021/ar040166v |
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Small Amphiphilic Organics, Coordination Extended Solids, and Constant Curvature Structures Stephen Lee, Abhijit Basu Mallik, Zhengtao Xu, Emil B. Lobkovsky, and Lieu Tran pp 251–261 DOI: 10.1021/ar0401653 |
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3-D Molecular Assembly of Function in Titania-Based Composite Material Systems Michael H. Bartl, Shannon W. Boettcher, Karen L. Frindell, and Galen D. Stucky pp 263–271 DOI: 10.1021/ar040177o |
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Design, Chirality, and Flexibility in Nanoporous Molecule-Based Materials D. Bradshaw, J. B. Claridge, E. J. Cussen, T. J. Prior, and M. J. Rosseinsky pp 273–282 DOI: 10.1021/ar0401606 |
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Microporous Porphyrin Solids Kenneth S. Suslick, P. Bhyrappa, J.-H. Chou, Margaret E. Kosal, Shirley Nakagaki, Dennis W. Smithenry, and Scott R. Wilson pp 283–291 DOI: 10.1021/ar040173j |
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The Interface Chemistry between Chalcogenide Clusters and Open Framework Chalcogenides Pingyun Feng, Xianhui Bu, and Nanfeng Zheng pp 293–303 DOI: 10.1021/ar0401754 |
Past, Present, and Future of Periodic Mesoporous Organosilicas The PMOsBenjamin Hatton, Kai Landskron, Wesley Whitnall, Douglas Perovic, and Geoffrey A. Ozin pp 305–312 DOI: 10.1021/ar040164a |
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Molecular Tectonics: From Simple Tectons to Complex Molecular Networks Mir Wais Hosseini pp 313–323 DOI: 10.1021/ar0401799 |
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Directed Assembly of Metal−Cyanide Cluster Magnets Lianne M. C. Beltran and Jeffrey R. Long pp 325–334 DOI: 10.1021/ar040158e |
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New Approaches to the Analysis of High Connectivity Materials: Design Frameworks Based upon 44- and 63-Subnet Tectons Robert J. Hill, De-Liang Long, Neil R. Champness, Peter Hubberstey, and Martin Schröder pp 335–348 DOI: 10.1021/ar040174b |
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Selective Molecular Recognition, C−H Bond Activation, and Catalysis in Nanoscale Reaction Vessels Dorothea Fiedler, Dennis H. Leung, Robert G. Bergman, and Kenneth N. Raymond pp 349–358 DOI: 10.1021/ar040152p |
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Structural Evolution and Phase Homologies for “Design” and Prediction of Solid-State Compounds Mercouri G. Kanatzidis pp 359–368 DOI: 10.1021/ar040176w |
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Coordination Assemblies from a Pd(II)-Cornered Square Complex Makoto Fujita, Masahide Tominaga, Akiko Hori, and Bruno Therrien pp 369–378 DOI: 10.1021/ar040153h |
Issue 05
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Why Enzymes Are Proficient Catalysts: Beyond the Pauling Paradigm Xiyun Zhang and K. N. Houk pp 379–385 DOI: 10.1021/ar040257s |
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Halogen Bonding Based Recognition Processes: A World Parallel to Hydrogen Bonding Pierangelo Metrangolo, Hannes Neukirch, Tullio Pilati, and Giuseppe Resnati pp 386–395 DOI: 10.1021/ar0400995 |
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Reflection on Medium Effects on Photochemical Reactivity Robert S. H. Liu and George S. Hammond pp 396–403 DOI: 10.1021/ar040246z |
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Conformationally Constrained PNA Analogues: Structural Evolution toward DNA/RNA Binding Selectivity Vaijayanti A. Kumar and Krishna N. Ganesh pp 404–412 DOI: 10.1021/ar030277e |
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The Virtue of Palladium-Catalyzed Domino Reactions − Diverse Oligocyclizations of Acyclic 2-Bromoenynes and 2-Bromoenediynes Armin de Meijere, Paultheo von Zezschwitz, and Stefan Bräse pp 413–422 DOI: 10.1021/ar980025r |
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Synthetic Strategies of Marine Polycyclic Ethers via Intramolecular Allylations: Linear and Convergent Approaches Isao Kadota and Yoshinori Yamamoto pp 423–432 DOI: 10.1021/ar040118a |
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Fifteen Years of Raman Spectroscopy of Engineered Heme Containing Peroxidases: What Have We Learned? Giulietta Smulevich, Alessandro Feis, and Barry D. Howes pp 433–440 DOI: 10.1021/ar020112q |
Issue 06
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Trans Lipids: The Free Radical Path Chryssostomos Chatgilialoglu and Carla Ferreri pp 441–448 DOI: 10.1021/ar0400847 |
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Chemistry of Squaraine-Derived Materials: Near-IR Dyes, Low Band Gap Systems, and Cation Sensors Ayyappanpillai Ajayaghosh pp 449–459 DOI: 10.1021/ar0401000 |
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Exploiting Synthetic Chemistry with Mesoionic Rings: Improvements Achieved with Thioisomünchnones Martín Ávalos, Reyes Babiano, Pedro Cintas, José L. Jiménez, and Juan C. Palacios pp 460–468 DOI: 10.1021/ar040212r |
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Lipid−Protein Interactions Revealed by Two-Photon Microscopy and Fluorescence Correlation Spectroscopy Susana A. Sánchez and Enrico Gratton pp 469–477 DOI: 10.1021/ar040026l |
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Polar Attributes of Supercritical Carbon Dioxide Poovathinthodiyil Raveendran, Yutaka Ikushima, and Scott L. Wallen pp 478–485 DOI: 10.1021/ar040082m |
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Photocontrolling Peptide α Helices G. Andrew Woolley pp 486–493 DOI: 10.1021/ar040091v |
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Strategies for Constructing Polymeric Micelles and Hollow Spheres in Solution via Specific Intermolecular Interactions Daoyong Chen and Ming Jiang pp 494–502 DOI: 10.1021/ar040113d |
Issue 07
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Single-Molecule Spectroscopy Paul F. Barbara pp 503–503 DOI: 10.1021/ar050120h |
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Free Energy Surfaces from Single-Molecule Force Spectroscopy Gerhard Hummer and Attila Szabo pp 504–513 DOI: 10.1021/ar040148d |
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Energy Dissipation in Multichromophoric Single Dendrimers F. C. De Schryver, T. Vosch, M. Cotlet, M. Van der Auweraer, K. Müllen, and J. Hofkens pp 514–522 DOI: 10.1021/ar040126r |
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Alternating-Laser Excitation of Single Molecules Achillefs N. Kapanidis, Ted A. Laurence, Nam Ki Lee, Emmanuel Margeat, Xiangxu Kong, and Shimon Weiss pp 523–533 DOI: 10.1021/ar0401348 |
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Single-Molecule Optoelectronics Tae-Hee Lee, Jose I. Gonzalez, Jie Zheng, and Robert M. Dickson pp 534–541 DOI: 10.1021/ar040146t |
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Surfaces and Orientations: Much to FRET about? Ivan Rasnik, Sean A. McKinney, and Taekjip Ha pp 542–548 DOI: 10.1021/ar040138c |
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Nonlinear Optical Chromophores as Nanoscale Emitters for Single-Molecule Spectroscopy Katherine A. Willets, Stefanie Y. Nishimura, P. James Schuck, Robert J. Twieg, and W. E. Moerner pp 549–556 DOI: 10.1021/ar0401294 |
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Probing Single-Molecule Protein Conformational Dynamics H. Peter Lu pp 557–565 DOI: 10.1021/ar0401451 |
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Single-Molecule RNA Folding Gregory Bokinsky and Xiaowei Zhuang pp 566–573 DOI: 10.1021/ar040142o |
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Fluorescence Imaging with One Nanometer Accuracy: Application to Molecular Motors Ahmet Yildiz and Paul R. Selvin pp 574–582 DOI: 10.1021/ar040136s |
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Rotational Motions of Macro- molecules by Single-Molecule Fluorescence Microscopy Stephanie A. Rosenberg, Margot E. Quinlan, Joseph N. Forkey, and Yale E. Goldman pp 583–593 DOI: 10.1021/ar040137k |
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Far-Field Optical Microscopy of Single Metal Nanoparticles Meindert A. van Dijk, Markus Lippitz, and Michel Orrit pp 594–601 DOI: 10.1021/ar0401303 |
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Single-Molecule Spectroscopy of Conjugated Polymers Paul F. Barbara, Andre J. Gesquiere, So-Jung Park, and Young Jong Lee pp 602–610 DOI: 10.1021/ar040141w |
Issue 08
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Comment on “Pallas and the Centaur” Luigi Fabbrizzi pp 611–611 DOI: 10.1021/ar050110g |
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Tailoring Porphyrins and Chlorins for Self-Assembly in Biomimetic Artificial Antenna Systems Teodor Silviu Balaban pp 612–623 DOI: 10.1021/ar040211z |
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Diverse World of Unconventional Hydrogen Bonds Natalia V. Belkova, Elena S. Shubina, and Lina M. Epstein pp 624–631 DOI: 10.1021/ar040006j |
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Toward the Ideal Organic Light-Emitting Diode. The Versatility and Utility of Interfacial Tailoring by Cross-Linked Siloxane Interlayers Jonathan G. C. Veinot and Tobin J. Marks pp 632–643 DOI: 10.1021/ar030210r |
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Bioinspired Surfaces with Special Wettability Taolei Sun, Lin Feng, Xuefeng Gao, and Lei Jiang pp 644–652 DOI: 10.1021/ar040224c |
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Toward Rapid, “Green”, Predictable Microwave-Assisted Synthesis Brett A. Roberts and Christopher R. Strauss pp 653–661 DOI: 10.1021/ar040278m |
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Mechanism for Transduction of the Ligand-Binding Signal in Heme-Based Gas Sensory Proteins Revealed by Resonance Raman Spectroscopy Takeshi Uchida and Teizo Kitagawa pp 662–670 DOI: 10.1021/ar030267d |
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Alfred Werner Revisited: The Coordination Chemistry of Anions Kristin Bowman-James pp 671–678 DOI: 10.1021/ar040071t |
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Generation of Cycloalkynes by Hydro-Iodonio-Elimination of Vinyl Iodonium Salts Tadashi Okuyama and Morifumi Fujita pp 679–686 DOI: 10.1021/ar040293r |
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A Carbon Nanotube-Based Coulter Nanoparticle Counter Takashi Ito, Li Sun, Ronald R. Henriquez, and Richard M. Crooks pp 687–687 DOI: 10.1021/ar050133v |
Issue 09
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Molecular Engineering of Octupolar NLO Molecules and Materials Based on Bipyridyl Metal Complexes Olivier Maury and Hubert Le Bozec pp 691–704 DOI: 10.1021/ar020264l |
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Selenium/Zeolite Y Nanocomposites Andreas Goldbach and Marie-Louise Saboungi pp 705–712 DOI: 10.1021/ar040282y |
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Arylation Reactions: The Photo-SN1 Path via Phenyl Cation as an Alternative to Metal Catalysis Maurizio Fagnoni and Angelo Albini pp 713–721 DOI: 10.1021/ar0402356 |
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Multivalency and Cooperativity in Supramolecular Chemistry Jovica D. Badjić, Alshakim Nelson, Stuart J. Cantrill, W. Bruce Turnbull, and J. Fraser Stoddart pp 723–732 DOI: 10.1021/ar040223k |
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Nucleophilic Substitution as a Tool for the Synthesis of Unsymmetrical Porphyrins Mathias O. Senge pp 733–743 DOI: 10.1021/ar0500012 |
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Functional Polyacetylenes Jacky W. Y. Lam and Ben Zhong Tang pp 745–754 DOI: 10.1021/ar040012f |
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Multiple Modes of Active Center Communication in Thiamin Diphosphate-Dependent Enzymes Frank Jordan, Natalia S. Nemeria, and Eduard Sergienko pp 755–763 DOI: 10.1021/ar040244e |
Issue 10
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Confinement of Metal Complexes within Porous Hosts: Development of Functional Materials for Gas Binding and Catalysis Leilani L. Welbes and A. S. Borovik pp 765–774 DOI: 10.1021/ar0402513 |
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Understanding How Cells Allocate Metals Using Metal Sensors and Metallochaperones Stephen Tottey, Duncan R. Harvie, and Nigel J. Robinson pp 775–783 DOI: 10.1021/ar0300118 |
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Catalytic Ethylene Dimerization and Oligomerization: Recent Developments with Nickel Complexes Containing P,N-Chelating Ligands Fredy Speiser, Pierre Braunstein, and Lucien Saussine pp 784–793 DOI: 10.1021/ar050040d |
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Evolution of Functional Cyclohexadiene-Based Synthetic Reagents: The Importance of Becoming Aromatic John C. Walton and Armido Studer pp 794–802 DOI: 10.1021/ar050089j |
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Attaching the Fluorine Atom to Organic Molecules Using BrF3 and Other Reagents Directly Derived from F2 Shlomo Rozen pp 803–812 DOI: 10.1021/ar040270c |
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Bioactive Substances from Insect Pathogenic Fungi Masahiko Isaka, Prasat Kittakoop, Kanyawim Kirtikara, Nigel L. Hywel-Jones, and Yodhathai Thebtaranonth pp 813–823 DOI: 10.1021/ar040247r |
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Alternating-Laser Excitation of Single Molecules Achillefs N. Kapanidis, Ted A. Laurence, Nam Ki Lee, Emmanuel Margeat, Xiangxu Kong, and Shimon Weiss: pp 824–824 DOI: 10.1021/ar050159m |
Issue 11
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Development of a Coordination Chemistry-Based Approach for Functional Supramolecular Structures Nathan C. Gianneschi, Martin S. Masar III, and Chad A. Mirkin pp 825–837 DOI: 10.1021/ar980101q |
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Reactions and Applications of Titanium Imido Complexes Nilay Hazari and Philip Mountford pp 839–849 DOI: 10.1021/ar030244z |
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Tandem Oxidation Processes Using Manganese Dioxide: Discovery, Applications, and Current Studies Richard J. K. Taylor, Mark Reid, Jonathan Foot, and Steven A. Raw pp 851–869 DOI: 10.1021/ar050113t |
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Carbon Nanotubes in Electron Donor−Acceptor Nanocomposites Dirk M. Guldi, G. M. A. Rahman, Francesco Zerbetto, and Maurizio Prato pp 871–878 DOI: 10.1021/ar040238i |
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Polyhedral Oligomeric Silsesquioxane Nanocomposites: The Next Generation Material for Biomedical Applications Ruben Y. Kannan, Henryk J. Salacinski, Peter E. Butler, and Alexander M. Seifalian pp 879–884 DOI: 10.1021/ar050055b |
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Exploring the Early Steps of Amyloid Peptide Aggregation by Computers Normand Mousseau and Philippe Derreumaux pp 885–891 DOI: 10.1021/ar050045a |
Issue 12
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Chemistry of Ice Surfaces. Elementary Reaction Steps on Ice Studied by Reactive Ion Scattering Heon Kang pp 893–900 DOI: 10.1021/ar0501471 |
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Molecules in Carbon Nanotubes Andrei N. Khlobystov, David A. Britz, and G. Andrew D. Briggs pp 901–909 DOI: 10.1021/ar040287v |
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Native State Kinetic Stabilization as a Strategy To Ameliorate Protein Misfolding Diseases: A Focus on the Transthyretin Amyloidoses Steven M. Johnson, R. Luke Wiseman, Yoshiki Sekijima, Nora S. Green, Sara L. Adamski-Werner, and Jeffery W. Kelly pp 911–921 DOI: 10.1021/ar020073i |
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Fluctuating Enzymes: Lessons from Single-Molecule Studies Wei Min, Brian P. English, Guobin Luo, Binny J. Cherayil, S. C. Kou, and X. Sunney Xie pp 923–931 DOI: 10.1021/ar040133f |
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Chemomechanical Functionalization and Patterning of Silicon Li Yang, Yit-Yian Lua, Michael V. Lee, and Matthew R. Linford pp 933–942 DOI: 10.1021/ar040242u |
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Metalloporphyrin−NO Bonding: Building Bridges with Organometallic Chemistry Abhik Ghosh pp 943–954 DOI: 10.1021/ar050121+ |
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Catalytic Reduction of Dinitrogen to Ammonia at a Single Molybdenum Center Richard R. Schrock pp 955–962 DOI: 10.1021/ar0501121 |